White light emitting devices having high luminous efficiency and improved color rendering that include pass-through violet emissions

ABSTRACT

A lighting apparatus a first group of at least one first solid state emitter, each first solid state emitter including a first light emitting diode (“LED”) that, when excited, emits light having a peak wavelength in a range between about 440 nm and about 475 nm, and a second group of at least one second solid state emitter, each second solid state emitter comprising a second LED that, when excited, emits light having a peak wavelength in a range between about 390 nm and about 415 nm. Between about 2% and about 15% of a spectral power of light emitted from the lighting apparatus is light having wavelengths in the range between about 390 nm and about 415 nm.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a continuation of U.S. patent application Ser. No.16/717,389, filed Dec. 17, 2019, entitled “WHITE LIGHT EMITTING DEVICESHAVING HIGH LUMINOUS EFFICIENCY AND IMPROVED COLOR RENDERING THATINCLUDE PASS-THROUGH VIOLET EMISSIONS,” which application is acontinuation of U.S. patent application Ser. No. 16/179,126, filed Nov.2, 2018 (now U.S. Pat. No. 10,546,843, issued Jan. 28, 2020), whichapplication claims priority under 35 U.S.C. § 119 to U.S. ProvisionalPatent Application Ser. No. 62/581,174, filed Nov. 3, 2017, the contentsof which are incorporated herein by reference as if set forth in theirentireties.

FIELD

The present disclosure relates to light emitting devices, and moreparticularly, to semiconductor light emitting devices that includeluminescent materials.

BACKGROUND

Light emitting devices may include, for example, incandescent bulbs,fluorescent lights, and semiconductor light emitting devices, such aslight emitting diodes (“LEDs”). LEDs may include a series ofsemiconductor layers that may be epitaxially grown on a substrate suchas, for example, a sapphire, silicon, silicon carbide, gallium nitride,or gallium arsenide substrate. One or more semiconductor p-n junctionsare formed in these epitaxial layers. When a sufficient voltage isapplied across the p-n junction, electrons in the n-type semiconductorlayers and holes in the p-type semiconductor layers flow toward the p-njunction. As the electrons and holes flow toward each other, theelectrons will “collide” with corresponding holes and recombine, suchthat a photon of light may be emitted. The wavelength distribution ofthe light generated by an LED generally depends on the semiconductormaterials used and the structure of the thin epitaxial layers that makeup the “active region” of the device, which is where the electron-holerecombination occurs.

LEDs are nearly monochromatic light sources that appear to emit lighthaving a single color. The spectral power distribution of the lightemitted by LEDs may be centered about a “peak” wavelength, which is thewavelength where the spectral power distribution or “emission spectrum”of the LED reaches its maximum as detected by a photodetector. The widthof the spectral power distribution of LEDs is typically between about 10nm and 30 nm, where the width may be measured at half of the maximumillumination on each side of the emission peak (this width may bereferred to as the full width at half maximum or “FWHM” width).

Visible light may include light having many different wavelengths. Theapparent color of visible light can be illustrated with reference to atwo-dimensional chromaticity diagram, such as the 1931 CIE ChromaticityDiagram illustrated in FIG. 1, which provides a reference for definingcolors as weighted sums of colors. As shown in FIG. 1, colors on the CIEChromaticity Diagram are defined by x and y coordinates (i.e.,chromaticity coordinates, or color points) that fall within a generallyU-shaped area. Colors on or near the outside of the area are saturatedcolors composed of light having a single wavelength, or a very smallwavelength distribution, while colors on the interior of the area areunsaturated colors that are composed of a mixture of differentwavelengths. White light, which can be a mixture of many differentwavelengths, is generally found near the middle of the diagram, in theregion labeled 10 in FIG. 1. There are many different hues of light thatmay be considered “white,” as evidenced by the size of the region 10.For example, some “white” light, such as light generated by high-powersodium vapor lighting devices, may appear yellowish in color, whileother “white” light, such as light generated by some fluorescentlighting devices, may appear more bluish in color.

A combination of light from light sources emitting light of first andsecond colors may appear to have a different color than either of thetwo constituent colors. The color of the combined light may depend onthe wavelengths and relative intensities of the two light sources. Forexample, light emitted by a combination of a blue source and a redsource may appear purple or magenta to an observer. Similarly, lightemitted by a combination of a blue source and a yellow source may appearwhite to an observer. Each point in the graph of FIG. 1 is referred toas the “color point” of a light source that emits a light having thatcolor. As shown in FIG. 1 a locus of color points that is referred to asthe “black-body” locus 15 exists which corresponds to the location ofcolor points of light emitted by a black-body radiator that is heated tovarious temperatures. The black-body locus 15 is also referred to as the“Planckian” locus because the chromaticity coordinates (i.e., colorpoints) that lie along the black-body locus obey Planck's equation:E(λ)=A λ⁻⁵/(e^(B/T)−1), where E is the emission intensity, X is theemission wavelength, T is the color temperature of the black-body and Aand B are constants. Color coordinates that lie on or near theblack-body locus 15 yield pleasing white light to a human observer.

As a heated object becomes incandescent, it first glows reddish, thenyellowish, and finally bluish with increasing temperature. This occursbecause the wavelength associated with the peak radiation of theblack-body radiator becomes progressively shorter with increasedtemperature, consistent with the Wien Displacement Law. Illuminants thatproduce light which is on or near the black-body locus 15 can thus bedescribed in terms of their correlated color temperature (CCT). As usedherein, the term “white light” refers to light that is perceived aswhite, is within 7 MacAdam ellipses of the black-body locus on a 1931CIE chromaticity diagram, and has a CCT ranging from 2000K to 10,000K.White light with a CCT of 4000K may appear yellowish in color, whilewhite light with a CCT of 8000K or more may appear more bluish in color,and may be referred to as “cool” white light. “Warm” white light may beused to describe white light with a CCT of between about 2500K and4500K, which is more reddish or yellowish in color.

SUMMARY

Various embodiments described herein provide lighting devices capable ofusing light having a peak wavelength in a range between about 390 nm andabout 415 nm to generate light that has an improved color renderingperformance.

According to some embodiments described herein, a light emitting deviceincludes: a first group of at least one first solid state emitter, eachfirst solid state emitter including a first blue light emitting diode(“LED”) that, when excited, emits light having a peak wavelength in ablue color range, and a first luminophoric medium that includes at leasta first luminescent material that, when excited by light from the firstblue LED, emits light having a peak wavelength in a green color range ora yellow color range, and a second luminescent material that, whenexcited by light from the first blue LED, emits light having a peakwavelength in an orange color range or a red color range; and a secondgroup of at least one second solid state emitter, each second solidstate emitter including a second LED that, when excited, emits lighthaving a peak wavelength in a range between about 390 nm and about 415nm, where between about 2% and about 15% of a spectral power of lightemitted from the light emitting device is light having wavelengths inthe range between about 390 nm and about 415 nm.

In some embodiments, the second luminescent material includes aK₂SiF₆:Mn⁴⁺ phosphor.

In some embodiments, the first luminescent material includes a YAG:Cephosphor.

In some embodiments, the second group of at least one second solid stateemitter does not include any associated luminophoric medium thereon.

In some embodiments, the second group of at least one second solid stateemitter further includes a second luminophoric medium.

In some embodiments, the second luminophoric medium is substantially thesame as the first luminophoric medium.

In some embodiments, the second luminophoric medium is different fromthe first luminophoric medium.

In some embodiments, the light emitting device is configured to emit thelight having a luminous flux efficiency of between 100 and 140 lumensper watt.

In some embodiments, the light emitting device is configured to emit thelight having the luminous flux efficiency of 120 lumens per watt with acolor rendering index (“CRI”) of at least 94.

In some embodiments, the second luminescent material includes anarrow-spectrum red phosphor.

In some embodiments, the light emitting device includes a first stringof solid state emitters connected electrically in series, the firststring of solid state emitters including at least one first solid stateemitter and at least one second solid state emitter.

In some embodiments, the light emitting device includes a first stringof solid state emitters connected electrically in series that includesat least one first solid state emitter and a second string of solidstate emitters connected electrically in series that includes at leastone second solid state emitter.

In some embodiments, a ratio of a first chip area of the first group ofat least one first solid state emitter to a second chip area of thesecond group of at least one second solid state emitter is between 2:1and 4:1.

In some embodiments, between about 3% and about 10% of the spectralpower of light emitted from the light emitting device is light havingwavelengths in the range between about 390 nm and about 415 nm.

In some embodiments, between about 2% and about 15% of the spectralpower of light emitted from the light emitting device is light havingwavelengths in the range between about 400 nm and about 410 nm.

In some embodiments, between about 4% and about 8% of the spectral powerof light emitted from the light emitting device is light havingwavelengths in the range between about 400 nm and about 410 nm.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in the green color rangewhile maintaining a luminous flux efficiency of the light emittingdevice between 100 lumens per watt and 140 lumens per watt.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in the yellow color range.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in the blue color rangewhile maintaining a luminous flux efficiency of the light emittingdevice between 100 lumens per watt and 140 lumens per watt.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in a violet color rangewhile maintaining a luminous flux efficiency of the light emittingdevice between 100 lumens per watt and 140 lumens per watt.

According to some embodiments described herein, a lighting apparatusincludes: a first group of at least one first solid state emitter, eachfirst solid state emitter including a first light emitting diode (“LED”)that, when excited, emits light having a peak wavelength in a rangebetween about 440 nm and about 475 nm; and a second group of at leastone second solid state emitter, each second solid state emitterincluding a second LED that, when excited, emits light having a peakwavelength in a range between about 390 nm and about 415 nm, wherebetween about 2% and about 15% of a spectral power of light emitted fromthe lighting apparatus is light having wavelengths in the range betweenabout 390 nm and about 415 nm.

In some embodiments, between about 2% and about 15% of the spectralpower of the light emitted from the lighting apparatus is light havingwavelengths in the range between about 400 nm and about 410.

In some embodiments, between about 2% and about 15% of the spectralpower of the light emitted from the lighting apparatus is light havingwavelengths in the range between about 402 nm and about 409.

In some embodiments, the lighting apparatus further comprises aluminophoric medium on the first LED or the second LED.

In some embodiments, the luminophoric medium comprises at least a firstluminescent material that, when excited by the light from the first LEDor the second LED, emits light having a peak wavelength in a yellowcolor range, and a second luminescent material that, when excited bylight from the first LED or the second LED, emits light having a peakwavelength in a red color range.

In some embodiments, the second luminescent material comprises aK₂SiF₆:Mn⁴⁺ phosphor.

In some embodiments, the first luminescent material comprises a YAG:Cephosphor.

In some embodiments, the first group and the second group areelectrically connected in series.

In some embodiments, the first group and the second group areelectrically connected in parallel.

In some embodiments, a first portion of the first group and a firstportion of the second group are electrically connected in series in afirst LED string, a second portion of the first group and a secondportion of the second group are electrically connected in series in asecond LED string, and the first LED string and the second LED stringare electrically connected in parallel.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the lighting apparatus in a green color range whilemaintaining a luminous flux efficiency of the lighting apparatus between100 lumens per watt and 140 lumens per watt.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the lighting apparatus in a yellow color range.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the lighting apparatus in a blue color range whilemaintaining a luminous flux efficiency of the lighting apparatus between100 lumens per watt and 140 lumens per watt.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the lighting apparatus in a violet color range whilemaintaining a luminous flux efficiency of the lighting apparatus between100 lumens per watt and 140 lumens per watt.

According to some embodiments described herein, a light emitting device,includes:

a first group of at least one first solid state emitter, each firstsolid state emitter including a first light emitting diode (“LED”) that,when excited, emits light having a peak wavelength in a range betweenabout 440 nm and about 475 nm; and a second group of at least one secondsolid state emitter, each second solid state emitter including a secondLED that, when excited, emits light having a peak wavelength in a rangebetween about 390 nm and about 415 nm, where the emission of the lightin the 390 nm to 415 nm wavelength range is configured to increase asaturation of a remainder of the emitted light of the light emittingdevice in a green-yellow color range by at least 10%.

In some embodiments, the light having wavelengths in the range betweenabout 390 nm and about 415 nm is configured to increase the saturationof the emitted light in the green-yellow color range while maintaining aluminous flux efficiency of the light emitting device between 100 lumensper watt and 140 lumens per watt.

In some embodiments, the light having wavelengths in the range betweenabout 390 nm and about 415 nm is configured to increase a saturation ofthe emitted light in a green color range while maintaining a luminousflux efficiency of the light emitting device between 100 lumens per wattand 140 lumens per watt.

In some embodiments, the light having wavelengths in the range betweenabout 390 nm and about 415 nm is configured to increase a saturation ofthe emitted light in a blue color range while maintaining a luminousflux efficiency of the light emitting device between 100 lumens per wattand 140 lumens per watt.

In some embodiments, the light having wavelengths in the range betweenabout 390 nm and about 415 nm is configured to increase a saturation ofthe emitted light in a violet color range while maintaining a luminousflux efficiency of the light emitting device between 100 lumens per wattand 140 lumens per watt.

In some embodiments, between about 2% and about 15% of the spectralpower of the light emitted from the light emitting device is lighthaving wavelengths in the range between about 400 nm and about 410.

In some embodiments, the light emitting device further includes aluminophoric medium on the first LED or the second LED.

In some embodiments, the luminophoric medium includes at least a firstluminescent material that, when excited by the light from the first LEDor the second LED, emits light having a peak wavelength in a yellowcolor range, and a second luminescent material that, when excited bylight from the first LED or the second LED, emits light having a peakwavelength in a red color range.

In some embodiments, the second luminescent material comprises aK₂SiF₆:Mn⁴⁺ phosphor.

In some embodiments, the first luminescent material comprises a YAG:Cephosphor.

In some embodiments, the emission of the light in the 390 nm to 415 nmwavelength range is configured to increase the saturation of theremainder of the emitted light of the light emitting device in the 4, 5,6, and 7 TM-30 hue angle bins by at least 10%.

In some embodiments, the emission of the light in the 390 nm to 415 nmwavelength range is configured to increase the saturation of theremainder of the emitted light of the light emitting device in the 8TM-30 hue angle bin by at least 5%.

According to some embodiments described herein, a light emitting device,includes:

a first group of at least one first solid state emitter, each firstsolid state emitter including a first blue light emitting diode (“LED”)that, when excited, emits light having a peak wavelength in a blue colorrange, and a first luminophoric medium; and a second group of at leastone second solid state emitter, each second solid state emitterincluding a second LED that, when excited, emits light having a peakwavelength in a range between about 390 nm and about 415 nm, wherein thesecond group of at least one second solid state emitter does not includeany associated luminophoric medium thereon.

In some embodiments, the first luminophoric medium comprises at least afirst luminescent material that, when excited by light from the firstblue LED, emits light having a peak wavelength in a green color range ora yellow color range, and a second luminescent material that, whenexcited by light from the first blue LED, emits light having a peakwavelength in an orange color range or a red color range.

In some embodiments, between about 2% and about 15% of a spectral powerof light emitted from the light emitting device is light havingwavelengths in the range between about 390 nm and about 415 nm.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in a green color rangewhile maintaining a luminous flux efficiency of the light emittingdevice between 100 lumens per watt and 140 lumens per watt.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in a yellow color range.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in the 4, 5, 6, and 7 TM-30hue angle bins by at least 10% while maintaining a luminous fluxefficiency of the light emitting between 100 lumens per watt and 140lumens per watt.

In some embodiments, exciting the second group of the at least onesecond solid state emitter is configured to increase a saturation of thelight emitted from the light emitting device in the 8 TM-30 hue anglebin by at least 5%.

In some embodiments, the light having a peak wavelength in the rangebetween about 390 nm and about 415 nm is emitted from the light emittingdevice without passing through a luminophoric medium

BRIEF DESCRIPTION OF THE DRAWINGS

The patent or application file contains at least one drawing executed incolor. Copies of this patent or patent application publication withcolor drawings will be provided by the Office upon request and paymentof the necessary fee.

FIG. 1 illustrates the 1931 CIE Chromaticity Diagram for defining colorsby chromaticity coordinates.

FIG. 2 is a graph illustrating color samples associated with the colorrendering index as a function of wavelength.

FIG. 3 is a graph of a luminosity function that corresponds to theresponse of the human eye to light in the visible light spectrum.

FIG. 4 is a graph illustrating an example of a spectral powerdistribution of a lighting device according to embodiments of thepresent invention.

FIGS. 5A, 5B, and 5C are schematic diagrams illustrating variouslighting devices utilizing configurations of first and second solidstate emitters according to embodiments of the present invention.

FIGS. 6A, 6B, and 6C are schematic diagrams illustrating various circuitconfigurations of first and second solid state emitters according toembodiments of the present invention.

FIG. 7 is a perspective view of a semiconductor light emitting deviceaccording to further embodiments of the present invention.

FIGS. 8A, 8B, and 8C are perspective views of a semiconductor lightemitting device according to further embodiments of the presentinvention.

FIG. 9A illustrates an example of a TM-30 color vector graphic,including a mapping between a test light source and a reference lightsource.

FIGS. 9B and 9C are TM-30 color vector graphics illustrating a colorrendering improvement achieved by lighting devices according toembodiments discussed herein.

It should be noted that these figures are intended to illustrate thegeneral characteristics of methods, structure, and/or materials utilizedin certain example embodiments and to supplement the written descriptionprovided below. These drawings are not, however, to scale and may notprecisely reflect the structural or performance characteristics of anygiven embodiment, and should not be interpreted as defining or limitingthe range of values or properties encompassed by example embodiments ofthe invention. For example, the relative thicknesses and positioning oflayers, regions, and/or structural elements may be reduced orexaggerated for clarity. The use of similar or identical referencenumbers in the various drawings is intended to indicate the presence ofa similar or identical element or feature.

DETAILED DESCRIPTION

As used herein, the term “light emitting device” may include LEDs, laserdiodes and any other semiconductor light emitting devices that includesone or more semiconductor layers, as well as packaged lamps, bulbs,fixtures and the like which include such semiconductor light emittingdevices. The semiconductor layers included in these devices may includesilicon, silicon carbide, gallium nitride and/or other semiconductormaterials, an optional semiconductor or non-semiconductor substrate, andone or more contact layers which may include metal and/or otherconductive materials. The expression “light emitting device” and/or“lighting apparatus,” as used herein, is not limited, except that it bea device that is capable of emitting light.

Semiconductor light emitting devices according to embodiments of thedisclosure may include III-V nitride (e.g., gallium nitride) based LEDsfabricated on a silicon carbide, sapphire or gallium nitride substratessuch as various devices manufactured and/or sold by Cree, Inc. ofDurham, N.C. Such LEDs may (or may not) be configured to operate suchthat light emission occurs through the substrate in a so-called “flipchip” orientation. Semiconductor light emitting devices according toembodiments of the present disclosure include both vertical devices witha cathode contact on one side of the LED, and an anode contact on anopposite side of the LED and devices in which both contacts are on thesame side of the device. The design and fabrication of semiconductorlight emitting devices are well known to those skilled in the art, andhence further description thereof will be omitted.

It will be understood that the term LED “string” refers to aconfiguration of LEDs that allows a respective current (such as afull-on current) to be enabled/disabled through that configurationseparately from enabling/disabling other respective currents throughother LED strings in the apparatus. A string can include at least oneLED device. Each string may include multiple LEDs that are connected invarious parallel and/or serial arrangements such that each string may beprovided with the respective full-on current for that string separatelyfrom the provisioning of the other LED strings. The strings of LEDs maybe configured in a number of different configurations. A lightingapparatus may include one or more LED strings, and may further include acontrol circuit configured to control a current and/or voltage providedto the one or more LED strings.

An LED can be characterized as having a particular spectral powerdistribution, which can affect various light characteristics of thelight emitted by the LED. It will be understood that a spectral powerdistribution can be used to express the power per unit area per unitwavelength of an illumination (radiant exitance). A lighting apparatusthat includes LEDs can also have a spectral power distribution which isa measure of the combined light emitted by the individual LEDs.

To generate white light, LED lamps have been provided that includeseveral LEDs that each emit light of a different color, where thedifferent-colored light emitted by the LEDs combine to produce a desiredintensity and/or color of white light. For example, simultaneouslyenergizing red, green, and blue LEDs may result in a combination oflight that may appear white, or nearly white, depending on, for example,the relative intensities, peak wavelengths, and spectral powerdistributions of the source red, green, and blue LEDs.

Additionally or alternatively, white light may also be produced bysurrounding a single LED with one or more luminescent materials, such asphosphors, that absorb some of the light emitted by the LED andresponsively emit light of one or more other colors. This process isalso referred to herein as “converting” some of the light emitted by theLED to the light of the other color(s). The combination of the lightemitted by the single colored LED that is not converted by luminescentmaterials and the light of other color(s) that are emitted by theluminescent materials may produce light that appears to be white or nearwhite to an observer. Herein, the term “phosphor” may refer to anymaterial that absorbs light at one wavelength and re-emits light at adifferent wavelength in the visible spectrum, regardless of the delaybetween absorption and re-emission and regardless of the wavelengthsinvolved. Thus, the term “phosphor” encompasses nanophosphors, quantumdots, and materials that are sometimes called fluorescent and/orphosphorescent.

Some white LEDs may use conventional rare earth doped inorganic red andgreen phosphors. For example, a nitride based red phosphor and a garnetgreen/yellow phosphor may be used in combination with a blue emittingLED to generate warm white light output. For instance, a white LED lampmay be formed by coating a gallium nitride based blue LED with a yellowluminescent material, such as a cerium doped yttrium aluminum garnetphosphor, which is commonly referred to as YAG:Ce. The blue LED producesan emission with a peak wavelength of, for example, about 460 nm. Someof the blue light emitted by the LED passes between and/or through theYAG:Ce phosphor particles without being down-converted (i.e., convertedto light having a longer wavelength), while other of the blue lightemitted by the LED is absorbed by the YAG:Ce phosphor, which becomesexcited and emits yellow fluorescence with a peak wavelength of about550 nm (i.e., the blue light is down-converted to yellow light). Thecombination of blue light and yellow light that is emitted by the coatedLED may appear white to an observer. Such light is typically perceivedas being cool white in color, as it is primarily comprises light on thelower half (shorter wavelength side) of the visible emission spectrum.To make the emitted white light appear more “warm” and/or exhibit bettercolor rendering properties, red-light emitting luminescent materialssuch as Eu²⁺ doped CaAlSiN₃-based phosphor particles may be added to thecoating.

A medium that includes one or more luminescent materials that ispositioned to receive light that is emitted by an LED or othersemiconductor light emitting device is referred to herein as a“luminophoric medium.” Exemplary luminophoric mediums include layershaving luminescent materials that are coated or sprayed directly onto asemiconductor light emitting device or on surfaces of the packagingthereof, and clear encapsulants (e.g., epoxy-based or silicone-basedcurable resin) that include luminescent materials that are arranged topartially or fully cover a semiconductor light emitting device. Aluminophoric medium may include one medium layer or the like in whichone or more luminescent materials are mixed, multiple stacked layers ormediums, each of which may include one or more of the same or differentluminescent materials, and/or multiple spaced apart layers or mediums,each of which may include the same or different luminescent materials.

Embodiments of the present invention are directed to semiconductor lightemitting devices that have LEDs and luminophoric mediums that includeluminescent materials that have peak emission wavelengths in variouscolor ranges. For purposes of this disclosure, the various color rangesof light in the visible and near-visible spectra are defined as shown inTable 1 below. It will be appreciated, however, that there are not sharpboundaries between different colors of the spectrum. For example, lighthaving wavelengths from 430-450 nm may appear blue-violet, while lighthaving wavelengths from 530-560 nm may appear yellow-green, etc.

TABLE 1 Color Wavelength Range (nm) Ultra-Violet/Violet 380-439 Blue440-479 Cyan 480-510 Green 511-549 Yellow 550-580 Orange 581-604 Red605-700

An LED or a luminescent material that emits light having a peakwavelength in one of the above color ranges may be referred to withreference to the color range. By way of example, a phosphor that emitslight having a peak wavelength of 630 nanometers may be referred toherein as a “red phosphor,” while a phosphor that emits light having apeak wavelength of 535 nanometers may be referred to as a “greenphosphor.”

A luminophoric medium that includes, for example, a yellow phosphor, maybe used in conjunction with a blue LED to provide a white light emittingdevice. Such a device typically emits cool white light that often has alower CRI value. The previously-described YAG:Ce is an example of such ayellow phosphor.

In order to increase the “warmth” of the emitted white light and/or toimprove the CRI of the device, red phosphor particles may be added tothe luminophoric medium. Nitride-based red phosphors often used have abroad emission spectrum (e.g., FWHM widths of greater than 70 nm) andrelatively high peak wavelengths (e.g., between about 630 nm and about660 nm). Other nitride-based red phosphors are available that have lowerpeak wavelengths (e.g., between about 611 nm and about 629 nm) andgenerally narrower emission spectrum (e.g., FWHM widths of between 35 nmand 40 nm). Herein, phosphors or other luminescent materials that haveFWHM widths of greater than or equal to about 70 nm are referred to as“broad-spectrum” luminescent materials or emitters. Luminescentmaterials that have an emission spectrum having a FWHM width of lessthan 70 nm are referred to herein as “narrow-spectrum” luminescentmaterials. Narrow-spectrum luminescent materials may also be used inconjunction with, or instead of, broad-spectrum luminescent materials.In some embodiments, a narrow-spectrum orange or red/orange emitter(e.g., having an emission peak in the 581-610 nm wavelength range) maybe used as one of the luminescent materials.

The ability of a light source to accurately reproduce color inilluminated objects is often characterized using the color renderingindex (CRI). The CRI of a light source is a modified average of therelative measurements of how the color rendition of an illuminationsystem compares to that of a reference black-body radiator whenilluminating eight reference colors. Thus, the CRI is a relative measureof the shift in surface color of an object when lit by a particularlamp. The CRI equals 100 if the color coordinates of a set of testcolors being illuminated by the illumination system are the same as thecoordinates of the same test colors being irradiated by the black-bodyradiator. Daylight generally has a CRI of nearly 100, incandescent bulbshave a CRI of about 95, fluorescent lighting typically has a CRI ofabout 70 to 85, while monochromatic light sources have a CRI ofessentially zero. Light sources for general illumination applicationswith a CRI of less than 50 are generally considered very poor and aretypically only used in applications where economic issues preclude otheralternatives. For some general interior illumination, a CRI value ofgreater than 80 may be acceptable. A light source with color coordinateswithin 4 MacAdam step ellipses of the Planckian locus 15 (FIG. 1) and aCRI value that exceeds 85 is more suitable for general illuminationpurposes. Light sources with CRI values of more than 90 provide greatercolor quality.

For general illumination and various other applications, it is oftendesirable to provide a lighting source that generates white light havinga relatively high CRI, so that objects illuminated by the lightingsource may appear to have more natural coloring to the human eye.

While CRI is useful in gauging the color rendering performance of alight source, standing alone, CRI may not always provide a satisfactorymeasure of the color quality. In particular, CRI is an average colorrendering value for eight specific sample colors that are generallyreferred to as R1-R8. FIG. 2 illustrates the color samples R1-R8 as afunction of wavelength. These eight color samples R1-R8 are primarilypastel shades, as opposed to saturated colors. As such, light emittingdevices that emit light having high CRI values may still fall short inrendering certain hues such as red hues. For example, the red content ofa light source may be important for accurately rendering colors ofvarious foods, skin tones, wood, furniture, and other objects. Only afew of the color samples used to compute CRI have significant redcontent (namely sample R1, which is a pink shade, and sample R8, whichis a purple shade), and these samples are not saturated color samples.As such, high CRI scores may be achieved even without significant redcontent in a light source, and thus a high CRI score may be achieved insome cases even though the light source may not do a good job ofrendering red hues.

In order to address this issue, seven additional color samples, labeledCRI R9-R15, have been defined that measure the color rendering of alight source for either saturated colors (R9-R12, corresponding tosaturated red, yellow, green and blue light) or for other colors(R13-R15) corresponding to two different skin tones and leaf green.These color samples are not used in calculating CRI, which is basedsolely on color samples R1-R8, but may be important when evaluating thecolor rendering performance of a particular light source. The samplecolor R9 is the saturated red color, and it is generally known that theability to reproduce red colors well is important for accuratelyrendering colors, as the color red is often found mixed into processedcolors. Accordingly, all else being equal, lamps with high R9 valuestend to produce the most vivid colors. Thus, the CRI R9 value of lightemitted by a light source is also often considered to be an importantperformance parameter for the light source. FIG. 2 also illustrates CRIR9 with respect to the other color samples R1-R8.

In addition, CRI also confers limited ability to predict colordiscrimination (i.e., to perceive subtle difference in hue) or colorpreference. There appears to be a natural human attraction to brightercolor. Daylight provides a spectrum of light that allows the human eyeto perceive bright and vivid colors, which allows a human observer todistinguish objects having even very subtle color shade differences.Accordingly, it is generally recognized that daylight and blackbodysources are superior to many artificial light sources for emphasizingand distinguishing color. The ability of human vision to differentiatecolor is different under correlated color temperature conditionsproviding the same CRI.

Another important performance parameter for an LED lighting source isthe intensity of the light emitted, which is referred to as the “radiantflux” of the device. However, as the human eye has varying sensitivityto different wavelengths of light, the intensity of the light emitted bya lighting source is most typically measured in terms of the lightingsource's “luminous flux,” which is a measure of the power of the lightemitted by a light source as perceived by a human observer. The luminousflux of a light source is typically measured in lumens (lm). Theluminous flux of a light source differs from the radiant flux of thelight source in that the radiant flux measures the total power emitted,while the luminous flux weights the power of the light emitted at eachwavelength based on a luminosity function which represents the responseof the human eye for each different wavelength.

FIG. 3 is a graph of the above-referenced luminosity function thatcorresponds to the response of the human eye to light in the visiblelight spectrum. As shown in FIG. 3, the human eye cannot typicallyperceive light at wavelengths below about 400 nanometers and above about700 nanometers. The maximum response of the human eye to light occurs atabout 555 nanometers. In calculating luminous flux, the radiant flux ofa light source is weighted based on the eye sensitivity curve of FIG. 3.As the amount of light emitted by an LED is generally a function of thepower input to the LED, the luminous flux performance of semiconductorlight emitting devices are typically compared with each device beingdriven at the same input power level or, alternatively, the devices maybe compared in terms of the luminous flux per unit of input power (e.g.,lumens per Watt) that each device emits at the input power level forwhich each device is designed to operate. As used herein, the term“luminous flux efficiency” will be used to denote luminous flux per unitof input power for a light emitting device.

Because of the varying sensitivity of the human eye to light ofdifferent wavelengths, there tends to be a tradeoff between the luminousflux of the light emitted by an LED lighting source and the CRI of thelight emitted. For example, since the human eye is most sensitive tolight at a wavelength of about 555 nm, a monochromatic light source at555 nm would exhibit a high luminous flux value. However, in order toobtain high CRI values, it is generally necessary to have lightcontribution across a wide range of wavelengths, including wavelengthsthat are relatively far away from 555 nm where the peak sensitivity oflight to the human eye occurs. This is particularly true with respect toCRI R9 performance which is a measure of color rendering in the redcolor range. Because the human eye has reduced sensitivity to thewavelengths on either end of the visible light spectrum, the lightcontributions that are often added to improve the CRI of a device mayresult in a decrease in the luminous flux efficiency of the device.

The above tradeoff is particularly evident for ultraviolet (UV)contributions of light from a lighting apparatus. As used herein, UVlight refers to light having a wavelength between about 390 nm and about415 nm. Because UV light is generally not visible or barely visible tothe human eye, it contributes little to the CRI score of emitted light.Similarly, because the human eye has little sensitivity for UV light,any power utilized to generate the UV light does not generate acorresponding perception in the human eye. As a result, the lumens perwatt of a lighting apparatus may decrease as the UV light emitted by thedevice increases.

However, the inventors have recognized a marked increase in perceivedquality of color rendered by light incorporating UV light in combinationwith other emitted light of a lighting apparatus. In particular, thoughthis UV light may not noticeably change the CRI rating of the lightingapparatus, incorporating UV light as a portion of the emitted light ofthe lighting apparatus results in a visibly different color rendering bythe light output that is immediately perceptible to humans. As notedabove, the CRI of a device does not always represent a true comparisonof how a human perceives color rendered by an emitted light. The presentinvention recognizes that, though providing a UV contribution iscounterintuitive to the composition of emitted LED light, it nonethelessmay provide markedly improved perceived color rendering if provided inthe correct amount and spectral range. For example, lighting devicesincorporating UV light as part of the emitted light results in whitelight that renders colors more crisply than emitted light without suchUV light.

FIG. 4 illustrates an example of a spectral power distribution of alighting device according to embodiments described herein. The spectralpower distribution of a lighting device that includes combinations ofLED strings can create an overall spectral power distribution for thelighting apparatus which can change based on which of the LED stringsare on and for how long each of the LED strings is on. This timingassociated with the LED strings having associated spectral powerdistributions can affect the lighting characteristics of the lightingapparatus including the CCT, the Color Quality Scale (CQS), the dominantwavelength, the GAI, peak wavelength, the S/P ratio, the nonlinearbrightness, the luminous efficacy, and the like. Other lightingcharacteristics can also be included within the definition of thespectral power distribution.

As shown in FIG. 4, the spectral power of emitted light according toembodiments of the invention may include several contributions. Forexample, the light output may have generally blue light 400 a (e.g.,light in the blue color range of wavelengths). The blue light 400 a mayinclude light having a peak emission near 450 nm. The light output mayalso include contributions in the green/yellow color range 400 b and inthe orange/red color range 400 c. As illustrated in FIG. 4, the lightcontributions in the green/yellow color range 400 b may be of a broaderspectrum than the contributions in the red/orange color range 400 c,though the embodiments described herein are not limited thereto.

As also illustrated in FIG. 4, the spectral power output may alsoinclude a UV contribution 400 d (e.g., light have a wavelength betweenabout 390 nm and about 415 nm). With respect to the total spectral poweroutput, the UV contribution 400 d may include between 2% and 15% of thetotal spectral power output. That is to say that the UV contribution ofthe total spectral power output of the lighting device may includebetween about 2% and about 15% of the area under the spectral powerdistribution curve of the lighting device. In some embodiments, thepercentage of the UV contribution may be between about 3% and about 10%of the total spectral power output. In some embodiments, the percentageof the UV contribution may be between about 4% and about 8% of the totalspectral power output.

In some embodiments, achieving the correct percentage of UV contributionmay include providing a lighting device with a ratio of light emittingchip area of 1:2 and 1:4 between UV light and light of otherwavelengths. In some embodiments, a light-emitting chip area ratio of1:3 between UV light and light of other wavelengths may be used.

Lighting devices utilizing a UV contribution to the emitted light asillustrated, for example, in FIG. 4 may be capable of generating lighthaving a CRI of between 90-99 with luminous flux performance between 100and 140 lumens per watt. In some embodiments, the lighting devices maybe capable of generating light having a CRI of between 90-99 withluminous flux performance between 100 and 150 lumens per watt. In someembodiments, the lighting devices may be capable of generating lighthaving a CRI of between 90-99 with luminous flux performance between 100and 160 lumens per watt.

To achieve the power distribution as shown in the example of FIG. 4, LEDchips emitting UV light may be combined with LEDs emitting otherwavelengths of light. For example, FIG. 5A illustrates a lighting device50 including a first solid state emitter 500 and a second solid stateemitter 510. The second solid state emitter 510 is configured to emit UVlight, and the first solid state emitter 500 is configured to emit lightof other wavelengths. As shown in FIG. 5A, the first solid state emitter500 includes a blue LED 560 and a luminophoric medium 570. Theluminophoric medium 570 may include one or more constituent materials.For example, in some embodiments, the luminophoric medium 570 mayinclude one or more layers of phosphors configured to convert some ofthe light emitted by the blue LEDs 560 to one or more differentwavelengths.

In the example illustrated in FIG. 5A, the luminophoric medium 570 mayinclude a first broad-spectrum phosphor 572 that emits light having apeak wavelength of about 550 nm (which may be in the green color rangeor the yellow color range depending upon the exact peak wavelength). Forexample, the first broad-spectrum phosphor 572 may be Y₃Al₅O₁₂:Ce(“YAG:Ce”), though the embodiments described herein are not limitedthereto. Other examples of luminescent materials include Lu₃Al₅O₁₂:Cephosphors (“LuAG:Ce”) and Y_(a)Ce_(b)Al_(c)Ga_(d)O_(z) phosphors(“gallium-substituted YAG:Ce”) that, when excited by light emitted by ablue LED, emit light having a peak wavelength in the green or yellowcolor ranges. These phosphors could be used instead of YAG:Ce phosphorsin any of the embodiments of the present invention described herein.

The luminophoric medium 570 may also include a second phosphor 574 thatemits light having a peak wavelength of between about 580 nm to 650 nm(which may be in the orange color range or the red color range dependingupon the exact peak wavelength). In some embodiments, the secondphosphor 574 may be a narrow-spectrum phosphor. Such narrow-spectrumorange emitters may provide higher efficacy than some conventionalphosphors, particularly as the converter efficiency of some conventionalred/orange-emitting phosphors is already close to unity, leaving littleroom to improve. Therefore, narrow-spectrum luminescent materials thatemit light in the orange or red/orange wavelength range can be used inaccordance with embodiments described herein to provide spectral (LER)and efficacy (LF) gains.

Specific examples of the narrow-spectrum down-converters/luminescentmaterials that may be used in light emitting devices according to someembodiments of the present disclosure may include, but are not limitedto: cadmium (Cd)-based quantum dots (QDs) (such as CdSe/CdS/SiO_(x),CdSe/CdS/ZnS/SiO_(x), CdSe/CdS/ZnS/SiO_(x)/ZnO, KASIL® encapsulated CdQDs, and/or other stabilized Cd QDs described in U.S. Patent ApplicationPublication No. 2017/0005241 filed Jun. 29, 2016, the disclosure ofwhich is incorporated by reference); Cd-free QDs (such as perovskite QDsand their stabilized structures, InP QDs and their stabilized structuresusing methods described in U.S. Patent Application Publication No.2017/0005241, and/or Cu-based QDs (e.g., CuIn(S/Se)₂) and theirstabilized structures using methods described in U.S. Patent ApplicationPublication No. 2017/0005241); and phosphors with narrow emission (suchas En³⁺ doped phosphors (e.g., Zn₂SnO₄:Eu³⁺), En²⁺ doped phosphors(e.g., CaS:Eu²⁺, SrS:Eu²⁺), Sm³⁺ doped phosphors, and/or other phosphorswith narrow emission in orange region of the spectrum). One example of anarrow-spectrum red luminescent material may include an A₂MF₆:Mn⁴⁺ redphosphor, where A is an Alkali metal and M is Si, Ge, Sn, Ti, Zr or Hf(e.g., K₂SiF₆:Mn⁴⁺). Though the first yellow/green phosphor layer 572and the second orange/red layer 574 are illustrated as an example, itwill be understood that other combinations of phosphors may be used.Similarly, though the luminophoric medium 570 is illustrated as havingtwo layers, it will be understood that a smaller number of layers (e.g.,a single layer) or a larger number of layers (e.g., greater than twolayers) may be provided without deviating from the present invention.

The second solid state emitter 510 includes a UV LED 580 and a clearencapsulant 584. The peak wavelength of the light emitted by the UV LED510 may be between about 390 nm and about 415 nm, and, in particular,between about 400 nm and about 410 nm. The clear encapsulant 584 mayinclude, for example, an epoxy-based or silicone-based curable resin,though the present invention is not limited thereto. In someembodiments, the clear encapsulant 584 may be omitted from the secondsolid state emitter 510. In some embodiments, UV LED 580 may emit UVlight (e.g., light have a wavelength between about 390 nm and about 415nm) from the lighting device 50 that does pass through a luminophoricmedium. For example, a luminophoric medium may be absent from the UV LED580, and the UV light emitted by the UV LED 580 may be emitted from thelighting device 50 without passing through a remote luminophoric medium.

Though the first solid state emitter 500 and the second solid stateemitter 510 are illustrated adjacent one another in FIG. 5A, it will beunderstood that this is only an example configuration. The arrangementof one or more first solid state emitters 500 and one or more secondsolid state emitters 510 may be made within a lighting device 50 in anyway understood to those of ordinary skill in the art so as to achievethe spectral power distribution of the lighting device 50 in whichbetween about 2% and about 15% of a spectral power of light emitted fromthe lighting device is light having wavelengths in the range betweenabout 390 nm and about 415 nm.

FIG. 5B illustrates additional embodiments of a lighting device 50′according to the present invention. As illustrated in FIG. 5B, a firstsolid state emitter 500′ includes the blue LED 560 with a firstluminophoric medium 594. The first luminophoric medium 594 may includeone or more luminescent materials configured to convert the lightemitted by the blue LED 560. For example, the first luminophoric medium594 may include layers and/or a mixture of one or more phosphors, suchas the broad-spectrum and/or narrow-spectrum phosphors described withrespect to FIG. 5A. In some embodiments, the first luminophoric medium594 may include fluorescent material (e.g., one or more phosphors)configured to convert the light emitted by the blue LED 560 to lighthaving a peak wavelength in the red or orange color ranges and/or tolight in the yellow or green color ranges, though the embodimentsdescribed herein are not limited thereto.

As also illustrated in FIG. 5B, the second solid state emitter 510′includes the UV LED 580 with a second luminophoric medium 595. Thesecond luminophoric medium 595 may include one or more luminescentmaterials configured to convert the light emitted by the UV LED 580. Forexample, the second luminophoric medium 595 may include layers and/or amixture of one or more phosphors, such as the broad-spectrum and/ornarrow-spectrum phosphors described with respect to FIG. 5A. In someembodiments, the second luminophoric medium 595 may include fluorescentmaterial (e.g., one or more phosphors) configured to convert the lightemitted by the UV LED 580 to light having a peak wavelength in the redor orange color ranges and/or to light in the yellow or green colorranges, though the embodiments described herein are not limited thereto.In some embodiments, the first luminophoric medium 594 and the secondluminophoric medium 595 may have substantially the same composition(i.e., may be substantially the same luminophoric medium). In someembodiments, the first luminophoric medium 594 and the secondluminophoric medium 595 may have different compositions.

FIG. 5C illustrates a lighting device 50″ according to additionalembodiments of the present invention. FIG. 5C differs from FIG. 5B inthat the first solid state emitter 500″ does not include a luminophoricmedium thereon. That is to say that the blue LED 560 may not have aconverting layer of fluorescent material on it.

The embodiments of FIGS. 5A, 5B, and 5C illustrate possibleconfigurations to generate UV light using various combinations ofluminophoric media. However, it will be understood by those of ordinaryskill in the art that other combinations are possible without deviatingfrom the scope and spirit of the present invention. Thus, theembodiments of the present invention are not strictly limited to theexamples illustrated herein. Rather, embodiments of the inventionencompass configurations of LEDs in a lighting device in which betweenabout 2% and about 15% of a spectral power of light emitted from thelighting device is light having wavelengths in the range between about390 nm and about 415 nm. For example, some embodiments of the inventionencompass configurations of LEDs in a lighting device in which betweenabout 3% and about 10% and/or 4% to 8% of a spectral power of lightemitted from the lighting device is light having wavelengths in therange between about 390 nm and about 415 nm. Some embodiments of theinvention encompass configurations of LEDs in a lighting device in whichbetween about 2% and about 15% of a spectral power of light emitted fromthe lighting device is light having wavelengths in the range betweenabout 400 nm and about 410 nm and/or 402 nm and about 409 nm.

FIGS. 6A, 6B, and 6C illustrate various circuit configurations in alighting device utilizing solid state emitters, such as the variationsof the first solid state emitter 500, 500′, 500″ and the second solidstate emitter 510, 510′ illustrated in FIGS. 5A, 5B, and 5C. Theseexamples are not intended to be limiting of the possible configurationsof the first and second solid state emitters 500, 500′, 500″, 510, 510′but rather provide example embodiments in which the first and secondsolid state emitters 500, 500′, 500″, 510, 510′ can be utilized. Thefirst solid state emitters 500, 500′, 500″ and second solid stateemitters 510, 510′ may be arranged within the lighting device to providepower to the first solid state emitters 500, 500′, 500″ and second solidstate emitters 510, 510′ that energizes the respective LEDs thereof suchthat between about 2% and about 15% of a spectral power of light emittedfrom the lighting device is light having peak wavelengths in the rangebetween about 390 nm and about 415 nm.

For example, FIG. 6A illustrates a lighting device 60 in which at leasta portion of the lighting device 60 includes a first string of firstsolid state emitters 600 and a second string of solid state emitters 610that are arranged electrically in parallel with one another. The firstsolid state emitters 600 may include any combination of the previousfirst solid state emitters 500, 500′, 500″ described herein with respectto FIGS. 5A, 5B, and/or 5C. The second solid state emitters 610 mayinclude any combination of the previous second solid state emitters 510,510′ described herein with respect to FIGS. 5A, 5B, and/or 5C. The firststring of first solid state emitters 600 may include a plurality offirst solid state emitters 600 electrically connected in series that areconfigured to emit light of one or more wavelengths. The second stringof second solid state emitters 610 may include a plurality of secondsolid state emitters 610 electrically connected in series that areconfigured to emit light of one or more wavelengths in the range betweenabout 390 nm and about 415 nm. Though each of the first and secondstrings is illustrated with three solid state emitters, it will berecognized that other configurations are possible. For example, thefirst LED string may have more or fewer than three first solid stateemitters 600. Similarly, the second LED string may have more or fewerthan three second solid state emitters 610. In some embodiments, thenumber of first solid state emitters 600 may be more or fewer than thenumber of second solid state emitters 610.

FIG. 6B illustrates a lighting device 60′ in which a portion of thelighting device 60′ includes at least one string with both first solidstate emitters 600 and solid state emitters 610 that are electricallyconnected in series. The first solid state emitters 600 may include anycombination of the previous first solid state emitters 500, 500′, 500″described herein with respect to FIGS. 5A, 5B, and/or 5C. The secondsolid state emitters 610 may include any combination of the previoussecond solid state emitters 510, 510′ described herein with respect toFIGS. 5A, 5B, and/or 5C. The first solid state emitters 600 and secondsolid state emitters 610 may be combined electrically in series invarious positions within the string. As illustrated in FIG. 6B, one ormore of the mixed strings may be arranged electrically in parallel,though the present invention is not limited thereto.

FIG. 6C illustrates a lighting device 60″ including a single string offirst solid state emitters 600 and solid state emitters 610 electricallyconnected in series. The first solid state emitters 600 may include anycombination of the previous first solid state emitters 500, 500′, 500″described herein with respect to FIGS. 5A, 5B, and/or 5C. The secondsolid state emitters 610 may include any combination of the previoussecond solid state emitters 510, 510′ described herein with respect toFIGS. 5A, 5B, and/or 5C. Such a configuration with a plurality of solidstate emitters 600, 610 connected electrically in series may be useful,for example, in so-called filament LEDs in which solid state emittersare arranged in a line to mimic the appearance of an incandescentfilament.

FIG. 7 is a perspective view of a semiconductor light emitting device700 according to further embodiments of the present invention. As shownin FIG. 7, the solid state light emitting device 700 includes asubstrate/submount (“submount”) 720 on which four LED chips or “die” 710are mounted. The submount 720 can be formed of many different materialssuch as, for example, aluminum oxide, aluminum nitride, organicinsulators, a printed circuit board (PCB), sapphire or silicon. The LEDs710 can have many different semiconductor layers arranged in differentways. The LEDs 710 may include UV LED 580 and/or blue LED 560 asdescribed herein with respect to FIGS. 5A, 5B, and 5C. LED structuresand their fabrication and operation are generally known in the art andhence are only briefly discussed herein. The layers of the LEDs 710 canbe fabricated using known processes such as, for example, metal organicchemical vapor deposition. Typically, LEDs are grown on a growthsubstrate such as, for example, a sapphire, silicon carbide, aluminumnitride (AlN), or gallium nitride (GaN) substrate to provide a grownsemiconductor wafer, and this wafer is then singulated into individualLED dies 710. The growth substrate can remain as part of the finalsingulated LED or, alternatively, the growth substrate can be fully orpartially removed. In embodiments where the growth substrate remains, itcan be shaped and/or textured to enhance light extraction. The LEDs 710may be mounted in flip chip configuration in some embodiments.

The LEDs 710 may each include a conductive current spreading structure712 on the respective top surfaces thereof, as well as one or morecontacts 714 that are accessible at its top surface for wire bonding. Inother embodiments, one or both contacts 714 for each LED 710 may be on abottom side of the LED. The current spreading structure 712 and contacts714 can both be made of a conductive material such as Au, Cu, Ni, In,Al, Ag or combinations thereof, conducting oxides and transparentconducting oxides. The current spreading structure 712 may compriseconductive fingers that are arranged in a pattern on each LED 710 withthe fingers spaced to enhance current spreading from the contacts 714into the top surface of the LEDs 710. In operation, an electrical signalis applied to the contacts 714 through a wire bond, and the electricalsignal spreads through the fingers of the current spreading structure712 into the LED 710.

Some or all of the LEDs 710 may be coated with a luminophoric medium 730according to embodiments of the present invention. It will be understoodthat the luminophoric medium 730 may comprise any of the luminophoricmediums discussed in the present application.

The luminophoric medium 730 may include a binder material, and may havedifferent concentrations or loading of phosphor materials in the binder,with a typical concentration being in range of 40-80% by weight. In oneembodiment, the phosphor concentration is approximately 75% by weight,and may be generally uniformly dispersed throughout the binder. In otherembodiments the luminophoric medium 730 can comprise multiple layers ofdifferent concentrations or types of phosphors (or other luminescentmaterials), and the multiple layers can comprise different bindermaterials. One or more of the layers can be provided without phosphors.For example, a first coat of clear silicone can be deposited followed byphosphor loaded layers.

The luminophoric medium 730 may be coated on the LEDs 710 using manydifferent methods. For example, in some embodiments, the luminophoricmedium 730 may be applied to semiconductor LED wafers during the LEDmanufacturing process. Suitable methods for such wafer level depositionare described in U.S. Patent Application Publication Nos. 2008/0173884,filed on Jan. 22, 2007, and 2008/0179611, filed on Sep. 7, 2007, bothentitled “Wafer Level Phosphor Coating Method and Devices FabricatedUtilizing Method.” Alternatively the luminophoric medium 730 may becoated on the LEDs 710 using other methods such an electrophoreticdeposition (EPD), with a suitable EPD method described in U.S. PatentApplication Publication No. 2007/0158668, filed on Jul. 12, 2007,entitled “Close Loop Electrophoretic Deposition of SemiconductorDevices.” In still other embodiments, the luminophoric medium 730 may besprayed or otherwise applied to the LEDs 710 after the LEDs 710 havebeen singulated and mounted on the mounting substrate 720. As describedherein, in some embodiments, the luminophoric medium 730 may not beapplied to certain ones of the LEDs 710. Numerous other techniques areknown in the art and are suitable for applying the recipientluminophoric mediums according to embodiments of the present invention.

An optical element or lens 740 is formed over at least part of the topsurface of the submount 720 to enclose the LEDs 710 and provide bothenvironmental and/or mechanical protection therefore. The lens 740 canbe molded using different molding techniques such as those described inU.S. Patent Application Publication No. 2009/0108281, filed on Apr. 30,2009, entitled “Light Emitting Diode Package and Method for FabricatingSame.” The lens 740 can be many different shapes such as, for example,hemispheric. Many different materials can be used for the lens 740 suchas silicones, plastics, epoxies, or glass. The lens 740 can also betextured to improve light extraction. In some embodiments, the lens 740may comprise the luminophoric medium 730 and/or may be used to hold aluminophoric medium 730 in place over the LEDs 710 instead of and/or inaddition to coating a luminophoric medium 730 directly onto the LEDchips 710.

FIGS. 8A, 8B, and 8C are perspective views of a semiconductor lightemitting device 800 according to further embodiments of the presentinvention. For example, referring to FIG. 8A, the semiconductor lightemitting device 800 may have an appearance that mimics a legacyincandescent bulb. The semiconductor light emitting device 800 includesan enclosure 802 and base 804, which may be configured as an Edison-typescrew connector. The base 804 may be configured to connect thesemiconductor light emitting device 800 to a power signal to activateone or more of the LEDs of the light emitting device 800. Though anEdison-type base 804 is illustrated in FIG. 8A, another type ofelectrical connector may be used as base 804 without deviating from thescope of the present invention.

The enclosure 802 may be made of a clear or diffused material. Thesemiconductor light emitting device 800 may be configured to emit lightthrough the enclosure 802. While the semiconductor light emitting device800 illustrated in FIG. 8A has the form factor of a candelabra bulb,other form factors are possible without deviating from the scope of thepresent invention.

The enclosure 802 houses an LED assembly 803 of LED filaments 820. Asused herein an LED filament 820 comprises a plurality of LEDselectrically connected together to form a filament-like chain or stringwhere the LEDs extend along the length of the LED filament such that theLED filament 820 has a relatively long and narrow configuration. Asillustrated in FIG. 8A, the LED filaments 820 may be arranged to extendgenerally parallel to a longitudinal axis of the semiconductor lightemitting device 800. The configuration of LED filaments 820 illustratedin FIG. 8A is an example configuration, and the present invention is notlimited thereto. LED filaments 820 according to embodiments of thepresent invention may take many different configurations. The LEDfilaments 820 may mimic the size and shape of an incandescent bulbfilament. In some embodiments, different ones of the plurality of LEDfilaments 820 may be configured to emit light that is different inintensity and/or color than other ones of the plurality of LED filaments820. That is to say that not all LED filaments 820 of the semiconductorlight emitting device 800 will share the same configuration.

An example embodiment of the LED filament 820 is shown in FIGS. 8B and8C. The LED filament 820 may include a substrate 822 that physicallysupports a plurality of LEDs 840. The LEDs 840 may include UV Led 580and/or blue LED 560 as described herein with respect to FIGS. 5A, 5B,and 5C. The LEDs 840 may, for example, be mounted on the substrate 822by an adhesive layer. In some embodiments, the LEDs 840 comprise LEDchips that are connected in series by wire bonds or other electricalconnection mechanisms such as, for example, a lead frame arrangement.

It should be noted that the term “substrate” as used herein is distinctfrom the semiconductor “substrate” layer of a chip such as the LEDs 840.The term “substrate” as used with respect to LED filaments such as thoseillustrated in FIGS. 8A, 8B, and 8C refers to substrate 822 and means asubmount, similar to the submount 720 of FIG. 7, for supporting multipleLEDs 840 in the LED filament 820. The substrate 822 may be of anysuitable material. For example, the substrate 822 may comprise glass,alumina, quartz or the like, or a metal such as aluminum or copper, andin some embodiments the substrate may be transparent.

As illustrated in FIGS. 8B and 8C, LED filament 820 includes a pluralityof LEDs 840 connected in series, though the present invention is notlimited thereto. In some embodiments, the LEDs 840 may be connected inseries in a configuration similar to that illustrated in FIG. 6C.However, the exact number of LEDs 840 and/or LED filaments 820 may varyfrom those of the illustration, and any number of LEDs 840 or devicescan be used, depending on the requirements and/or constraints of thesemiconductor light emitting device 800. Pads 816 and 818 may befastened to the ends of the substrate 822, one on each end. Each pad mayprovide an electrical connection point to the filament-like chain ofLEDs 840. The pads 816, 818 may then be electrically coupled to the base804 to complete the electrical path from the base 804 to the LEDs 840 toprovide power to the LEDs 840.

The LEDs may be surrounded by or encapsulated in a luminophoric medium830. It will be understood that the luminophoric medium 830 may compriseany of the luminophoric mediums discussed in the present application.Though illustrated in FIGS. 8B and 8C as a common luminophoric medium830, it will be understood that, in some embodiments, the luminophoricmedium 830 may be separately applied to one or more of the LEDs 840.Similarly, in some embodiments, some of the LEDs 840 may be at leastpartially covered by the luminophoric medium 830, and some of the LEDs840 may not be covered by the luminophoric medium 830. In someembodiments, some of the LEDs 840 may be at least partially covered by afirst luminophoric medium 830, and some of the LEDs 840 at leastpartially covered by a second luminophoric medium, different from thefirst luminophoric medium 830.

Note that in some of the FIGS. 8A, 8B, and 8C, the sizes and spacing ofLEDs 840 and other components may be enlarged for clarity. The figuresare schematic in nature and may not be to scale.

Referring again to FIG. 8A, in some embodiments the enclosure 802 may besealed to the base 804 to create an airtight seal therebetween. Theinterior space 808 of the enclosure 802 may be filled with a heatconductive gas 810 such as, for example, helium, argon, nitrogen, or thelike to create a more efficient heat conductive path between the LEDassembly 803 and the enclosure 802 to facilitate the transfer of heataway from the LEDs 840. Though helium, argon, and nitrogen are listed asexamples of the heat conductive gas 810, the present invention is notlimited thereto.

FIGS. 9A, 9B, and 9C illustrate, in part, a color vector graphic basedon the Illuminating Engineering Society (IES) TM-30-15 (“TM-30”) methodfor evaluating light source color rendering. TM-30 is a method forevaluating light source color rendering that includes numerous measuresthat quantify different aspects of color rendering, such as fidelity andgamut. In contrast to TM-30, CRI is purely a method for evaluating colorfidelity. TM-30 does include a fidelity measure, although it isdifferent from CRI in some ways.

One drawback of a metric such as CRI, which focuses on color fidelity,is that it does not provide information related to color distortion. Forexample, two light sources may have the same CRI value, but the outputof the two light sources may be noticeably different if one of the lightsources is saturating, for example, a red color as compared to the otherlight source. The light source with the saturated red color may be morevisually appealing as compared to the light source that was notsaturating, or desaturating, that color.

To address this, a metric related to gamut may be used. This metricexpresses the extent of average color saturation or desaturation for alight source compared to a reference source. TM-30 uses the samereference source as is used for CRI. The reference source ismathematically derived, and is representative of non-electric, “natural”lighting. TM-30 compares the color rendition of a test source to thereference source at the same correlated color temperature (CCT). Forsources with a CCT of 4500 K or less, the reference source is aPlanckian radiator—at the right CCT this is essentially an incandescentlamp. At 5500 K or above, the reference source is the CIE D Series, amathematical model of daylight. Between 4500 K and 5500 K, the referencesource is a proportional blend of Planckian radiation and the D Seriesilluminant, each at the specified CCT. For example, at 4750 K, thereference illuminant is 75% Planckian radiation (at 4750 K) and 25% CIED Series illuminant (at 4750 K).

The TM-30 method uses a color gamut metric Rg. If Rg is higher than 100,the light source is producing an average increase in saturation withrespect to the reference source. If Rg is lower than 100, the lightsource is producing an average decrease in saturation with respect tothe reference source.

TM-30 also provides a color vector graphic. The color vector graphic isa visual representation of hue and chroma shifts for all colors of atest source light. The graphical representation is based on the averagechromaticity coordinates calculated for the color evaluation samples ineach of 16 hue angle bins. The color vector graphic may quickly conveywhat types of colors are more or less saturated under the test lightsource relative to the reference illuminant and where hue shifts occur.These specific changes may be helpful to understanding what source willbe preferred in a given application. Sub-indices for fidelity and chromashift (i.e., saturation change) in each hue angle bin are related to thevectors displayed in the color vector graphic.

FIG. 9A illustrates an example of a TM-30 color vector graphic,including a mapping between a test light source and a reference lightsource. In the color vector graphic, the reference illuminant isrepresented by the black circle 910. In each of the 16 hue angle bins920 (see graph on right side of FIG. 9A), the average shift created bythe test source relative to the reference source for the samples in thebin is plotted with arrows. The ends of the areas are connected to forma shape 915 that characterizes the test source gamut. The test sourceillustrated in FIG. 9A is for example purposes only.

Where the line for the test source 915 is outside the circle 910, thetest source is saturating colors in that hue range. Likewise, where theline for the test source 915 is inside the circle 900, the test sourceis desaturating those hues relative to the reference source. Arrows thatare not perpendicular to the circle 900 indicate that a hue shift isalso occurring (e.g., reds shifting to orange-reds).

FIG. 9B illustrates a TM-30 color vector graphic for a lighting devicewithout a substantial UV contribution. The lighting device used for atest source in FIG. 9B includes a blue LED with a peak wavelength of 450nm, including a YAG:CE phosphor and a K₂SiF₆:Mn⁴⁺ phosphor. In thiscase, there is essentially no light emission having peak wavelengths inthe range between about 390 nm and about 415 nm. As can be seen in thecolor vector graphic of FIG. 9B, the color rendering of the light isslightly oversaturated in green color ranges 900 g and blue/violet colorranges 900 b. These oversaturated values correspond, for example, atleast in part to TM-30 hue angle bins of 6, 7, 12, and 13 (see FIG. 9A).The color rendering in the test source of FIG. 9B is slightlydesaturated in red color ranges 900 r, which corresponds, for example,at least in part to TM-30 hue angle bin 1.

The TM-30 color vector graphic of FIG. 9B has been separated into fourquadrants labeled A, B, C, and D. Quadrant A represents ranges of colorhues contributing to the green/yellow color rendering and corresponds toTM-30 hue angle bins 5, 6, 7, and 8. Quadrant B represents ranges ofcolor hues contributing to the orange/yellow color rendering andcorresponds to TM-30 hue angle bins 1, 2, 3, and 4. Quadrant Crepresents ranges of color hues contributing to the violet/red colorrendering and corresponds to TM-30 hue angle bins 9, 10, 11, and 12.Quadrant D represents ranges of color hues contributing to the bluecolor rendering and corresponds to TM-30 hue angle bins 13, 14, 15, and16.

FIG. 9C illustrates a TM-30 color vector graphic for the same lightingdevice of FIG. 9B in which an additional UV contribution of 7.5% hasbeen added. That is to say that the light having peak wavelengths in therange between about 390 nm and about 415 nm makes up about 7.5% of aspectral power of light emitted from the lighting device. The UVcontribution was provided by a UV LED, such as UV LED 580 of FIGS. 5A,5B, and 5C without a luminophoric medium thereon.

As can be seen from FIG. 9C, the addition of the UV contribution to thespectral power distribution of the lighting device has provided anunexpected beneficial effect. The addition of the UV contribution to theemitted light has resulted in an increase in the oversaturation of theboth the green color ranges 900 g′ as well as the blue/violet colorranges 900 b′. In addition, the addition of the UV contribution hasresulted in oversaturation in the red color ranges 900 r′ andoversaturation in the yellow color ranges 900 y that was not previouslypresent. Referring to FIGS. 9C and 9A, the increase in oversaturationoccurs roughly in quadrants A and D of the TM-30 color vector graphic,though the present invention is not limited thereto. In the exampleillustrated in FIG. 9C, an increase in saturation can be seen in TM-30hue angle bins 4, 5, 6, 7, 8, 13, and 15, though the present inventionis not limited thereto. The hue angle bins 4, 5, 6, 7, and 8 representcolors in the green-yellow color range. In some embodiments, the UVcontribution may increase a saturation of the light emitting device inthe green-yellow color range by at least 10% as compared to the samelight emitting device without the UV contribution. In some embodiments,the UV contribution may increase a saturation of the light emittingdevice in hue angle bins 4-7 by at least 10% and hue angle bin 8 by atleast 5% as compared to the same light emitting device without the UVcontribution.

Because the UV contribution in the wavelengths of between about 390 nmand about 415 nm are on the outer fringes of the sensitivity of thehuman eye (see FIG. 3), the increase in the saturation of theabove-discussed visible areas of the color ranges is unexpected.Moreover, since saturated color can be perceived by the human eye asmore attractive, especially colors in the green-yellow range, therelatively small contribution of UV light described herein can result ina significant increase in perceived color rendering performance for thelight. The embodiments of the present invention described herein resultfrom a recognition by the inventors that such a counterintuitiveapplication of light having peak wavelengths in the range between about390 nm and about 415 nm results in a light that has a higher perceivedcolor rendering performance. Lighting devices utilizing this recognitionmay be made higher performing with little additional package design, asthe UV LEDs described herein may be incorporated within an existing LEDconfiguration in any number of ways.

Techniques as described herein improve the operation of any solid-stateemitters configured to generate white light. For example, the techniquesdescribed herein may include providing a UV contribution having a peakwavelength of between about 390 nm and about 415 nm in combination witha blue LED having a luminophoric medium that includes a LuAG:Ce orYAG:Ce phosphor and a broad-spectrum red phosphor such as(Ca_(1-x)Sr_(x))SiAlN₃:Eu²⁺. For example, the techniques described heremay also include providing a UV contribution having a peak wavelength ofbetween about 390 nm and about 415 nm in combination with a blue LEDhaving a luminophoric medium that includes a LuAG:Ce or YAG:Ce phosphorand a narrow-spectrum red phosphor such as K₂SiF₆:Mn^(4±). For example,the techniques described here may also include providing a UVcontribution having a peak wavelength of between about 390 nm and about415 nm in combination with a blue LED having a luminophoric medium thatincludes a LuAG:Ce or YAG:Ce phosphor and a red AlInGaP LED.

Many different embodiments have been disclosed herein, in connectionwith the above description and the drawings. It will be understood thatit would be unduly repetitious and obfuscating to literally describe andillustrate every combination and subcombination of these embodiments.Accordingly, the present specification, including the drawings, shall beconstrued to constitute a complete written description of allcombinations and subcombinations of the embodiments described herein,and of the manner and process of making and using them, and shallsupport claims to any such combination or subcombination.

The present invention has been described above with reference to theaccompanying drawings, in which certain embodiments are shown. However,this disclosure should not be construed as limited to the embodimentsset forth herein. Rather, these embodiments are provided so that thisdisclosure will be thorough and complete, and will fully convey thescope of the disclosure to those skilled in the art. In the drawings,the thickness of layers and regions are exaggerated for clarity. Likenumbers refer to like elements throughout. As used herein the term“and/or” includes any and all combinations of one or more of theassociated listed items.

The terminology used herein is for the purpose of describing particularembodiments only and is not intended to be limiting of the presentinvention. As used herein, the singular forms “a”, “an” and “the” areintended to include the plural forms as well, unless the context clearlyindicates otherwise. It will be further understood that, when used inthis specification, the terms “comprises” and/or “including” andderivatives thereof, specify the presence of stated elements and/orcomponents, but do not preclude the presence or addition of one or moreother elements, components, and/or groups thereof.

It will be understood that when an element such as a layer, region, orsubstrate is referred to as being “on” or extending “onto” anotherelement, it can be directly on or extend directly onto the other elementor intervening elements may also be present. In contrast, when anelement is referred to as being “directly on” or extending “directlyonto” another element, there are no intervening elements present. Itwill also be understood that when an element is referred to as being“connected” or “coupled” to another element, it can be directlyconnected or coupled to the other element or intervening elements may bepresent. In contrast, when an element is referred to as being “directlyconnected” or “directly coupled” to another element, there are nointervening elements present.

It will be understood that, although the terms first, second, etc. maybe used herein to describe various elements, components, regions and/orlayers, these elements, components, regions and/or layers should not belimited by these terms. These terms are only used to distinguish oneelement, component, region or layer from another element, component,region or layer. Thus, a first element, component, region, or layerdiscussed below could be termed a second element, component, region, orlayer without departing from the teachings of the present invention.

Furthermore, relative terms, such as “lower” or “bottom” and “upper” or“top,” may be used herein to describe one element's relationship toanother element as illustrated in the figures. It will be understoodthat relative terms are intended to encompass different orientations ofthe device in addition to the orientation depicted in the figures. Forexample, if the device in the figures is turned over, elements describedas being on the “lower” side of other elements would then be oriented on“upper” sides of the other elements. The exemplary term “lower”, cantherefore, encompasses both an orientation of “lower” and “upper,”depending on the particular orientation of the figure.

Embodiments of the disclosure are described herein with reference tocross-section illustrations that are schematic illustrations ofidealized embodiments (and intermediate structures) of the disclosure.The thickness of layers and regions in the drawings may be exaggeratedfor clarity. Additionally, variations from the shapes of theillustrations as a result, for example, of manufacturing techniquesand/or tolerances, are to be expected. Thus, embodiments of thedisclosure should not be construed as limited to the particular shapesof regions illustrated herein but are to include deviations in shapesthat result, for example, from manufacturing.

In the drawings and specification, there have been disclosed embodimentsof the disclosure and, although specific terms are employed, they areused in a generic and descriptive sense only and not for purposes oflimitation, the scope of the disclosure being set forth in the followingclaims.

That which is claimed:
 1. A light emitting device, comprising: a firstgroup of at least one first solid state emitter, each first solid stateemitter comprising a first light emitting diode (“LED”) that, whenexcited, emits light having a peak wavelength in a blue color range, anda first luminophoric medium that includes at least a first luminescentmaterial that, when excited by light from the first LED, emits lighthaving a peak wavelength in a green color range or a yellow color range,and a second luminescent material that, when excited by light from thefirst LED, emits light having a peak wavelength in an orange color rangeor a red color range; and a second group of at least one second solidstate emitter, each second solid state emitter comprising a second LEDthat, when excited, emits light having a peak wavelength in a rangebetween about 390 nm and about 415 nm, wherein between about 2% andabout 15% of a spectral power of light emitted from the light emittingdevice is light having wavelengths in the range between about 390 nm andabout 415 nm.
 2. The light emitting device of claim 1, wherein thesecond group of at least one second solid state emitter does not includeany associated luminophoric medium thereon.
 3. The light emitting deviceof claim 1, wherein the second group of at least one second solid stateemitter further comprises a second luminophoric medium.
 4. The lightemitting device of claim 3, wherein the second luminophoric medium issubstantially the same as the first luminophoric medium.
 5. The lightemitting device of claim 1, wherein the light emitting device isconfigured to emit the light having a luminous flux efficiency ofbetween 100 and 140 lumens per watt.
 6. The light emitting device ofclaim 5, wherein the light emitting device is configured to emit thelight having a color rendering index (“CRI”) of at least
 94. 7. Thelight emitting device of claim 1, wherein the second luminescentmaterial comprises a narrow-spectrum red phosphor.
 8. The light emittingdevice of claim 1, wherein a ratio of a first chip area of the firstgroup of at least one first solid state emitter to a second chip area ofthe second group of at least one second solid state emitter is between2:1 and 4:1.
 9. The light emitting device of claim 1, wherein betweenabout 2% and about 15% of the spectral power of light emitted from thelight emitting device is light having wavelengths in the range betweenabout 400 nm and about 410 nm.
 10. A light emitting device, comprising:an enclosure; at least one first solid state emitter and at least onesecond solid state emitter within the enclosure; and a base coupled tothe enclosure, the base configured to electrically connect the at leastone first solid state emitter and the at least one second solid stateemitter to a power source, wherein the at least one first solid stateemitter comprises a first light emitting diode (“LED”) that, whenexcited, emits light having a peak wavelength in a blue color range; andwherein the at least one second solid state emitter comprises a secondLED that, when excited, emits light having a peak wavelength in a rangebetween about 390 nm and about 415 nm, and wherein between about 2% andabout 15% of a spectral power of light emitted from the light emittingdevice is light having wavelengths in the range between about 390 nm andabout 415 nm.
 11. The light emitting device of claim 10, wherein the atleast one first solid state emitter further comprises a firstluminophoric medium that includes at least a first luminescent materialthat, when excited by light from the first LED, emits light having apeak wavelength in a green color range or a yellow color range, and asecond luminescent material that, when excited by light from the firstLED, emits light having a peak wavelength in an orange color range or ared color range.
 12. The light emitting device of claim 10, wherein thebase is configured as an Edison-type screw connector.
 13. The lightemitting device of claim 10, wherein the at least one second solid stateemitter does not include any associated luminophoric medium thereon. 14.The light emitting device of claim 10, wherein the at least one secondsolid state emitter further comprises a second luminophoric medium. 15.The light emitting device of claim 14, wherein the second luminophoricmedium comprises at least a first luminescent material that, whenexcited by light from the second LED, emits light having a peakwavelength in a green color range or a yellow color range, and a secondluminescent material that, when excited by light from the second LED,emits light having a peak wavelength in an orange color range or a redcolor range.
 16. The light emitting device of claim 10, wherein thelight emitting device is configured to emit the light having a luminousflux efficiency of between 100 and 140 lumens per watt.
 17. The lightemitting device of claim 10, wherein the light emitting device isconfigured to emit the light having a color rendering index (“CRI”) ofat least
 94. 18. A method of manufacturing a light emitting device,comprising: providing at least one first solid state emitter comprisinga first light emitting diode (“LED”) that, when excited, emits lighthaving a peak wavelength in a blue color range; providing at least onesecond solid state emitter comprising a second LED that, when excited,emits light having a peak wavelength in a range between about 390 nm andabout 415 nm; depositing a first luminophoric medium on the at least onefirst solid state emitter, the first luminophoric medium comprising atleast a first luminescent material that, when excited by light from thefirst LED, emits light having a peak wavelength in a green color rangeor, a yellow color range, and a second luminescent material that, whenexcited by light from the first LED, emits light having a peakwavelength in an orange color range or a red color range; and providinga control circuit configured to operate the at least one first solidstate emitter and the at least one second solid state emitter such thatbetween about 2% and about 15% of a spectral power of light emitted fromthe light emitting device is light having wavelengths in the rangebetween about 390 nm and about 415 nm.
 19. The method of claim 18,further comprising depositing a second luminophoric medium on the atleast one second solid state emitter further.
 20. The method of claim19, wherein the second luminophoric medium is substantially the same asthe first luminophoric medium.